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Mechanosynthesis of Odd‐Numbered Tetraaryl[n]cumulenes

A mechanochemical synthesis of one‐dimensional carbon allotrope carbyne model compounds, namely tetraaryl[n]cumulenes (n=3, 5) was realized. Central for the mechanosynthesis of the cumulenic carbon nanostructures were the development of a mechanochemical Favorskii alkynylation‐type reaction and the...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Ardila‐Fierro, Karen J., Bolm, Carsten, Hernández, José G.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6773223/
https://ncbi.nlm.nih.gov/pubmed/31265746
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201905670
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