Unusual Length Dependence of the Conductance in Cumulene Molecular Wires

Cumulenes are sometimes described as “metallic” because an infinitely long cumulene would have the band structure of a metal. Herein, we report the single‐molecule conductance of a series of cumulenes and cumulene analogues, where the number of consecutive C=C bonds in the core is n=1, 2, 3, and 5....

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Xu, Wenjun, Leary, Edmund, Hou, Songjun, Sangtarash, Sara, González, M. Teresa, Rubio‐Bollinger, Gabino, Wu, Qingqing, Sadeghi, Hatef, Tejerina, Lara, Christensen, Kirsten E., Agraït, Nicolás, Higgins, Simon J., Lambert, Colin J., Nichols, Richard J., Anderson, Harry L.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6563095/
https://ncbi.nlm.nih.gov/pubmed/31026371
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201901228
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