O−O Bond Formation and Liberation of Dioxygen Mediated by N(5)‐Coordinate Non‐Heme Iron(IV) Complexes

Formation of the O−O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are commonly regarded as instrumental for oxygen evolution, but direct experimental evidence is lacking. Herein, we describe the fo...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Kroll, Nicole, Speckmann, Ina, Schoknecht, Marc, Gülzow, Jana, Diekmann, Marek, Pfrommer, Johannes, Stritt, Anika, Schlangen, Maria, Grohmann, Andreas, Hörner, Gerald
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772150/
https://ncbi.nlm.nih.gov/pubmed/31271694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903902
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