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O−O Bond Formation and Liberation of Dioxygen Mediated by N(5)‐Coordinate Non‐Heme Iron(IV) Complexes
Formation of the O−O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are commonly regarded as instrumental for oxygen evolution, but direct experimental evidence is lacking. Herein, we describe the fo...
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| Опубликовано в: : | Angew Chem Int Ed Engl |
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| Главные авторы: | , , , , , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
John Wiley and Sons Inc.
2019
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6772150/ https://ncbi.nlm.nih.gov/pubmed/31271694 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903902 |
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