O−O Bond Formation and Liberation of Dioxygen Mediated by N(5)‐Coordinate Non‐Heme Iron(IV) Complexes

Formation of the O−O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are commonly regarded as instrumental for oxygen evolution, but direct experimental evidence is lacking. Herein, we describe the fo...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Kroll, Nicole, Speckmann, Ina, Schoknecht, Marc, Gülzow, Jana, Diekmann, Marek, Pfrommer, Johannes, Stritt, Anika, Schlangen, Maria, Grohmann, Andreas, Hörner, Gerald
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2019
Fag:
Research Articles
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772150/
https://ncbi.nlm.nih.gov/pubmed/31271694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903902
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