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O−O Bond Formation and Liberation of Dioxygen Mediated by N(5)‐Coordinate Non‐Heme Iron(IV) Complexes

Formation of the O−O bond is considered the critical step in oxidative water cleavage to produce dioxygen. High‐valent metal complexes with terminal oxo (oxido) ligands are commonly regarded as instrumental for oxygen evolution, but direct experimental evidence is lacking. Herein, we describe the fo...

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Библиографические подробности
Опубликовано в: :Angew Chem Int Ed Engl
Главные авторы: Kroll, Nicole, Speckmann, Ina, Schoknecht, Marc, Gülzow, Jana, Diekmann, Marek, Pfrommer, Johannes, Stritt, Anika, Schlangen, Maria, Grohmann, Andreas, Hörner, Gerald
Формат: Artigo
Язык:Inglês
Опубликовано: John Wiley and Sons Inc. 2019
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6772150/
https://ncbi.nlm.nih.gov/pubmed/31271694
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903902
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