Treatment of Silylene–Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon‐Bonded Chalcogens

Chalcogen‐bonded silicon phosphinidenes LSi(E)−P−(Me)cAAC (E=S (1); Se (2); Te (3); L=PhC(NtBu)(2); (Me)cAAC=C(CH(2))(CMe(2))(2)N‐2,6‐iPr(2)C(6)H(3))) were synthesized from the reactions of silylene–phosphinidene LSi−P−(Me)cAAC (A) with elemental chalcogens. All the compounds reported herein have be...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Sinhababu, Soumen, Siddiqui, Mujahuddin M., Sarkar, Samir Kumar, Münch, Annika, Herbst‐Irmer, Regine, George, Anjana, Parameswaran, Pattiyil, Stalke, Dietmar, Roesky, Herbert W.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6771779/
https://ncbi.nlm.nih.gov/pubmed/31282057
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902661
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