A Neutral Three‐Membered 2π Aromatic Disilaborirane and the Unique Conversion into a Four‐Membered BSi(2)N‐Ring

We report the design, synthesis, structure, bonding, and reaction of a neutral 2π aromatic three‐membered disilaborirane. The disilaborirane is synthesized by a facile one‐pot reductive dehalogenation of amidinato‐silylene chloride and dibromoarylborane with potassium graphite. Despite the tetravale...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Sarkar, Samir Kumar, Chaliha, Rinkumoni, Siddiqui, Mujahuddin M., Banerjee, Samya, Münch, Annika, Herbst‐Irmer, Regine, Stalke, Dietmar, Jemmis, Eluvathingal D., Roesky, Herbert W.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7756765/
https://ncbi.nlm.nih.gov/pubmed/32840959
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202009638
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