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Practical Catalytic Cleavage of C(sp(3))−C(sp(3)) Bonds in Amines

The selective cleavage of thermodynamically stable C(sp(3))−C(sp(3)) single bonds is rare compared to their ubiquitous formation. Herein, we describe a general methodology for such transformations using homogeneous copper‐based catalysts in the presence of air. The utility of this novel methodology...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Li, Wu, Liu, Weiping, Leonard, David K., Rabeah, Jabor, Junge, Kathrin, Brückner, Angelika, Beller, Matthias
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6771714/
https://ncbi.nlm.nih.gov/pubmed/31125156
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201903019
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