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Catalytic Enantioselective Synthesis of 1,4-Keto-Alkenylboronate Esters and 1,4-Dicarbonyls.

A catalytic enantioselective method for the synthesis of 1,4-ketoalkenylboronate esters via a rhodium-catalyzed conjugate addition pathway is disclosed. A variety of novel, bench-stable alkenyl gem-diboronate esters are synthesized. These easily accessible reagents react smoothly with a collection o...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Liang, Michael Z., Meek, Simon J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6764896/
https://ncbi.nlm.nih.gov/pubmed/31353794
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201907757
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