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Catalytic Enantioselective Synthesis of 1,4-Keto-Alkenylboronate Esters and 1,4-Dicarbonyls.
A catalytic enantioselective method for the synthesis of 1,4-ketoalkenylboronate esters via a rhodium-catalyzed conjugate addition pathway is disclosed. A variety of novel, bench-stable alkenyl gem-diboronate esters are synthesized. These easily accessible reagents react smoothly with a collection o...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6764896/ https://ncbi.nlm.nih.gov/pubmed/31353794 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201907757 |
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