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Total Synthesis of Pentacyclic (–)-Ambiguine P Using Sequential Indole Functionalizations
The first synthesis of a pentacyclic ambiguine (ambiguine P) is reported. The synthesis takes advantage of sequential alkylations of an indole core to rapidly construct the pentacyclic framework of the natural product. Key to the success of the synthesis was the use of a Nicholas reaction to alkylat...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6742481/ https://ncbi.nlm.nih.gov/pubmed/30702879 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b13388 |
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