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Synthesis of the ABC- and D-Ring Systems of the Indole Alkaloid Ambiguine G

[Image: see text] A glycine Schiff base Michael addition is used in sequence with free radical-mediated aryl amination to ultimately arrive at the ambiguine G ABC-tricycle convergently. Additionally, thermal Diels-Alder cycloaddition of β-chloro methacrolein with Cohen’s diene is used to diastereose...

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Autori principali: Chandra, Aroop, Viswanathan, Rajesh, Johnston, Jeffrey N.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2007
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2617716/
https://ncbi.nlm.nih.gov/pubmed/17975918
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol702247a
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