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Tropane alkaloids biosynthesis involves an unusual type III polyketide synthase and non-enzymatic condensation
The skeleton of tropane alkaloids is derived from ornithine-derived N-methylpyrrolinium and two malonyl-CoA units. The enzymatic mechanism that connects N-methylpyrrolinium and malonyl-CoA units remains unknown. Here, we report the characterization of three pyrrolidine ketide synthases (PYKS), AaPYK...
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| Publicado no: | Nat Commun |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group UK
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6731253/ https://ncbi.nlm.nih.gov/pubmed/31492848 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-11987-z |
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