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Ground State Destabilization in Uracil DNA Glycosylase: Let Us Not Forget “Tautomeric Strain” in Substrates
Enzymes like uracil DNA glycosylase (UDG) can achieve ground state destabilization, by polarizing substrates to mimic rare tautomers. On the basis of computed nucleus independent chemical shifts, NICS(1)(zz), and harmonic oscillator model of electron delocalization (HOMED) analyses, of quantum mecha...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6726543/ https://ncbi.nlm.nih.gov/pubmed/31434485 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b06447 |
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