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Computational Mechanistic Insights on the NO Oxidation Reaction Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes

The conversion reaction of NO to NO(3)(−) ion catalyzed by the end-on [Cr(III)(n-TMC)(O(2))(Cl)](+) superoxo and side-on [Cr(IV)(n-TMC)(O(2))(Cl)](+) peroxo non-heme complexes (n = 12, 13, 14 and 15), which are biomimetic systems of nitric oxide dioxygenases (NODs), has been explored using a computa...

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Bibliographische Detailangaben
Veröffentlicht in:Int J Mol Sci
Hauptverfasser: Marino, Tiziana, Fortino, Maria Grazia, Russo, Nino, Toscano, Marirosa, Alberto, Marta Erminia
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI 2019
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6721035/
https://ncbi.nlm.nih.gov/pubmed/31416223
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ijms20163955
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