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Formamide catalyzed activation of carboxylic acids – versatile and cost-efficient amidation and esterification
A novel, broadly applicable method for amide C–N and ester C–O bond formation is presented based on formylpyrrolidine (FPyr) as a Lewis base catalyst. Herein, trichlorotriazine (TCT), which is the most cost-efficient reagent for OH-group activation, was employed in amounts of ≤40 mol% with respect t...
में बचाया:
| में प्रकाशित: | Chem Sci |
|---|---|
| मुख्य लेखकों: | , |
| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
Royal Society of Chemistry
2019
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6713870/ https://ncbi.nlm.nih.gov/pubmed/31489162 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02126d |
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