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A Gallium-based Chiral Solvating Agent Enables the Use of (1)H NMR Spectroscopy to Differentiate Chiral Alcohols

In situ, direct (1)H NMR chiral analysis by using chiral solvating agents is a convenient and efficient analytical technique. Here we developed a Ga-based chiral anionic metal complex for (1)H NMR chiral analysis of alcohols. Utilizing the optimal pK(a) value, the Ga complex was able to differentiat...

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Detalhes bibliográficos
Publicado no:iScience
Main Authors: Jang, Sumin, Kim, Hyunwoo
Formato: Artigo
Idioma:Inglês
Publicado em: Elsevier 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6704394/
https://ncbi.nlm.nih.gov/pubmed/31421597
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.isci.2019.07.051
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