Crystal structures of DOTMA chelates from Ce(3+) to Yb(3+): evidence for a continuum of metal ion hydration states

The crystal structures of chelates formed between each stable paramagnetic lanthanide ion and DOTMA are described. A total of 23 individual chelates structures were obtained, in each chelate the coordination geometry around the metal ion is best described as a twisted square antiprism (torsion angle...

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Bibliographic Details
Published in:Chemistry
Main Authors: Woods, Mark, Payne, Katherine M., Valente, Edward J., Kucera, Benjamin E., Young, Victor G.
Format: Artigo
Language:Inglês
Published: 2019
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6700027/
https://ncbi.nlm.nih.gov/pubmed/31121070
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902068
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