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Visible Light‐Promoted Beckmann Rearrangements: Separating Sequential Photochemical and Thermal Phenomena in a Continuous Flow Reactor

The Beckmann rearrangement of oximes to amides typically requires strong acids or highly reactive, hazardous electrophiles and/or elevated temperatures to proceed. A very attractive alternative is the in situ generation of Vilsmeier–Haack reagents, by means of photoredox catalysis, as promoters for...

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Detalhes bibliográficos
Publicado no:European J Org Chem
Main Authors: Chen, Yuesu, Cantillo, David, Kappe, C. Oliver
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6686973/
https://ncbi.nlm.nih.gov/pubmed/31423105
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201900231
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