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Controlling, understanding, and redirecting the thermal rearrangement of 3,3-dicyano-1,5-enynes
The thermal [3,3] rearrangement of 3,3-di-cyano-1,5-enynes to γ-allenyl alkylidenemalononitriles (the “enyne Cope rearrangement”) has largely eluded synthetic value as the desired products, too, are thermally reactive and ultimately yield 6π electrocyclization products. Herein, we describe experimen...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6679653/ https://ncbi.nlm.nih.gov/pubmed/30379070 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08553 |
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