Učitavanje...
Controlling, understanding, and redirecting the thermal rearrangement of 3,3-dicyano-1,5-enynes
The thermal [3,3] rearrangement of 3,3-di-cyano-1,5-enynes to γ-allenyl alkylidenemalononitriles (the “enyne Cope rearrangement”) has largely eluded synthetic value as the desired products, too, are thermally reactive and ultimately yield 6π electrocyclization products. Herein, we describe experimen...
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| Izdano u: | J Am Chem Soc |
|---|---|
| Glavni autori: | , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2018
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6679653/ https://ncbi.nlm.nih.gov/pubmed/30379070 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b08553 |
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