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A Nitrone Dipolar Cycloaddition Strategy toward an Enantioselective Synthesis of Massadine
An enantioselective route to the C,D-bicycle of massadine is reported. Enantiopure intermediates were generated by a single stereoselective reduction using the Corey–Bakshi–Shibata reagent. This initial stereoinduction was translated into the five contiguous stereocenters of the massadine D-ring by...
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| Publicado no: | Org Lett |
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| Autor principal: | |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6674976/ https://ncbi.nlm.nih.gov/pubmed/29897770 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b01464 |
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