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Asymmetric Catalysis in Chiral Solvents: Chirality Transfer with Amplification of Homochirality through a Helical Macromolecular Scaffold

[Image: see text] Use of chiral solvents in asymmetric synthesis as a sole source of enantioselection remains largely unexplored in organic synthesis. We found that the use of a helical macromolecular catalyst of which helical chirality is dynamically formed in chiral solvents allowed several mechan...

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Bibliographic Details
Published in:ACS Cent Sci
Main Authors: Nagata, Yuuya, Takeda, Ryohei, Suginome, Michinori
Format: Artigo
Language:Inglês
Published: American Chemical Society 2019
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6661863/
https://ncbi.nlm.nih.gov/pubmed/31404214
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.9b00330
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