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Crystal structures of two Cu(II) compounds: catena-poly[[chlorido­copper(II)]-μ-N-[eth­oxy(pyridin-2-yl)methyl­idene]-N′-[oxido(pyridin-3-yl)methyl­idene]hydrazine-κ(4) N,N′,O:N′′] and di-μ-chlorido-1:4κ(2) Cl:Cl-2:3κ(2) Cl:Cl-di­chlorido-2κCl,4κCl-bis[μ(3)-eth­oxy(pyridin-2-yl)methano­lato-1:2:3κ(3) O:N,O:O;1:3:4κ(3) O:O:N,O]bis­[μ(2)-eth­oxy(pyridin-2-yl)methano­lato-1:2κ(3) N,O:O;3:4κ(3) N,O:O]tetracopper(II)

Two Cu(II) complexes [Cu(C(14)H(13)N(4)O(2))Cl](n), I, and [Cu(4)(C(8)H(10)NO(2))(4)Cl(4)](n), II, have been synthesized. In the structure of the mononuclear complex I, each ligand is coordinated to two metal centers. The basal plane around the Cu(II) cation is formed by one chloride anion, one oxyg...

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Bibliographic Details
Published in:Acta Crystallogr E Crystallogr Commun
Main Authors: Sall, Ousmane, Tamboura, Farba Bouyagui, Sy, Adama, Barry, Aliou Hamady, Thiam, Elhadj Ibrahima, Gaye, Mohamed, Ellena, Javier
Format: Artigo
Language:Inglês
Published: International Union of Crystallography 2019
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6659337/
https://ncbi.nlm.nih.gov/pubmed/31392027
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989019008922
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