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Crystal structures of two Cu(II) compounds: catena-poly[[chlorido­copper(II)]-μ-N-[eth­oxy(pyridin-2-yl)methyl­idene]-N′-[oxido(pyridin-3-yl)methyl­idene]hydrazine-κ(4) N,N′,O:N′′] and di-μ-chlorido-1:4κ(2) Cl:Cl-2:3κ(2) Cl:Cl-di­chlorido-2κCl,4κCl-bis[μ(3)-eth­oxy(pyridin-2-yl)methano­lato-1:2:3κ(3) O:N,O:O;1:3:4κ(3) O:O:N,O]bis­[μ(2)-eth­oxy(pyridin-2-yl)methano­lato-1:2κ(3) N,O:O;3:4κ(3) N,O:O]tetracopper(II)

Two Cu(II) complexes [Cu(C(14)H(13)N(4)O(2))Cl](n), I, and [Cu(4)(C(8)H(10)NO(2))(4)Cl(4)](n), II, have been synthesized. In the structure of the mononuclear complex I, each ligand is coordinated to two metal centers. The basal plane around the Cu(II) cation is formed by one chloride anion, one oxyg...

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Publicado en:Acta Crystallogr E Crystallogr Commun
Autores principales: Sall, Ousmane, Tamboura, Farba Bouyagui, Sy, Adama, Barry, Aliou Hamady, Thiam, Elhadj Ibrahima, Gaye, Mohamed, Ellena, Javier
Formato: Artigo
Lenguaje:Inglês
Publicado: International Union of Crystallography 2019
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC6659337/
https://ncbi.nlm.nih.gov/pubmed/31392027
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989019008922
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