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Iodine-Mediated Oxidative Rearrangement of α,β-Unsaturated Diaryl Ketones: A Facile Access to 1,2-Diaryl Diketones

[Image: see text] A metal-free oxidative rearrangement was explored for the synthesis of 1,2-diaryl diketones by utilizing α,β-unsaturated diaryl ketones and I(2)/TBHP in good to high yields. The reaction proceeds via oxidative aryl migration, followed by C–C bond cleavage. A simple and high-yieldin...

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Detalles Bibliográficos
Publicado en:ACS Omega
Main Authors: Bansode, Ajay H., Suryavanshi, Gurunath
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2019
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6648810/
https://ncbi.nlm.nih.gov/pubmed/31460054
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b00833
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