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Indium-Mediated 2-Oxonia Cope Rearrangement of 1,4-Dienols to 1,3-Dienols

[Image: see text] An indium-mediated isomerization of 1,4-dienols to 1,3-dienols is described. This procedure consists of the addition of pentadienylindium, in a protic solvent, to aldehydes giving the kinetic γ-allylation product in high yields. The subsequent conversion of this γ-allylation produc...

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Pubblicato in:ACS Omega
Autori principali: Capel, Natalie J., Lindley, Martin R., Pritchard, Gareth J., Kimber, Marc C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2019
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6648455/
https://ncbi.nlm.nih.gov/pubmed/31459359
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b03118
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