Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement

Rearrangement reactions have attracted considerable interest over the past decades due to their high bond-forming efficiency and atom economy in the construction of complex organic architectures. In contrast to the well-established [3,3]-rearrangement, [1,3] O-to-C rearrangement has been far less vi...

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Pubblicato in:Nat Commun
Autori principali: Zhou, Bo, Zhang, Ying-Qi, Zhang, Kairui, Yang, Ming-Yang, Chen, Yang-Bo, Li, You, Peng, Qian, Zhu, Shou-Fei, Zhou, Qi-Lin, Ye, Long-Wu
Natura: Artigo
Lingua:Inglês
Pubblicazione: Nature Publishing Group UK 2019
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6642132/
https://ncbi.nlm.nih.gov/pubmed/31324800
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-11245-2
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