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Stereoselective Synthesis of Homofarnesenes: Establishment of an Efficient Method for the Stereoselective Preparation of Acyclic Tetrasubstituted Olefins
[Image: see text] A new method for the stereoselective synthesis of tetrasubstituted olefins is described. β-Ketophosphonates are alkylated via conventional methods, and a Grignard reagent is used to diastereoselectively add to the carbonyl group of the resulting intermediates. The elimination of hy...
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| Published in: | ACS Omega |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical Society
2018
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6641643/ https://ncbi.nlm.nih.gov/pubmed/31458678 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b00439 |
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