Stereoselective Synthesis of Homofarnesenes: Establishment of an Efficient Method for the Stereoselective Preparation of Acyclic Tetrasubstituted Olefins

[Image: see text] A new method for the stereoselective synthesis of tetrasubstituted olefins is described. β-Ketophosphonates are alkylated via conventional methods, and a Grignard reagent is used to diastereoselectively add to the carbonyl group of the resulting intermediates. The elimination of hy...

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Bibliographic Details
Published in:ACS Omega
Main Authors: Yin, Wenhao, Liang, Weihong, Guo, Liping, Lei, Jiaheng, Qiu, Fayang G.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2018
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6641643/
https://ncbi.nlm.nih.gov/pubmed/31458678
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.8b00439
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