Platinum Complexes with Chelating Acyclic Aminocarbene Ligands Work as Catalysts for Hydrosilylation of Alkynes

[Image: see text] This work describes the preparation of a series of platinum–aminocarbene complexes [PtCl{C(N=C(a)(C(6)R(2)R(3)R(4)R(5)CON(b)))=N(H)R(1)}(CNR(1))](a–b) (8–19, 65–75% isolated yield) via the reaction of cis-[PtCl(2)(CNR(1))(2)] (R(1) = Cy 1, t-Bu 2, Xyl 3, 2-Cl-6-MeC(6)H(3)4) with 3-...

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Publicat a:ACS Omega
Autors principals: Chay, Rogério S., Rocha, Bruno G. M., Pombeiro, Armando J. L., Kukushkin, Vadim Yu., Luzyanin, Konstantin V.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2018
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6641237/
https://ncbi.nlm.nih.gov/pubmed/31457933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b01688
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