Protein modification via alkyne hydrosilylation using a substoichiometric amount of ruthenium(ii) catalyst

Transition metal catalysis has emerged as a powerful strategy to expand synthetic flexibility of protein modification. Herein, we report a cationic Ru(ii) system that enables the first example of alkyne hydrosilylation between dimethylarylsilanes and O-propargyl-functionalized proteins using a subst...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Kwan, Terence T.-L., Boutureira, Omar, Frye, Elizabeth C., Walsh, Stephen J., Gupta, Moni K., Wallace, Stephen, Wu, Yuteng, Zhang, Fengzhi, Sore, Hannah F., Galloway, Warren R. J. D., Chin, Jason W., Welch, Martin, Bernardes, Gonçalo J. L., Spring, David R.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5578368/
https://ncbi.nlm.nih.gov/pubmed/28966779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05313k
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