Enantioselective PCCP Brønsted acid-catalyzed aza-Piancatelli rearrangement

An enantioselective aza-Piancatelli rearrangement has been developed using a chiral Brønsted acid based on pentacarboxycyclopentadiene (PCCP). This reaction provides rapid access to valuable chiral 4-amino-2-cyclopentenone building blocks from readily available starting material and is operationally...

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Detalles Bibliográficos
Publicado en:Beilstein J Org Chem
Main Authors: Hammersley, Gabrielle R, Nichol, Meghan F, Steffens, Helena C, Delgado, Jose M, Veits, Gesine K, Read de Alaniz, Javier
Formato: Artigo
Idioma:Inglês
Publicado: Beilstein-Institut 2019
Assuntos:
Letter
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6633596/
https://ncbi.nlm.nih.gov/pubmed/31354876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.15.160
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