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Achiral Counterion Control of Enantioselectivity in a Brønsted Acid Catalyzed Iodolactonization
Highly enantioselective halolactonizations have been developed using a chiral proton catalyst NIS reagent system in which the Brønsted acid is used at catalyst loadings as low as 1 mol%. An approach that modulates the achiral counterion (equimolar to the neutral chiral ligand proton complex present...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3326820/ https://ncbi.nlm.nih.gov/pubmed/22463391 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja301858r |
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