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Chromium-Salen Catalyzed Cross-Coupling of Phenols: Mechanism and Origin of the Selectivity
A highly chemoselective phenol cross-coupling reaction catalyzed by a Cr-salen catalyst was developed. Kinetic studies showed that the oxidation of Cr(III) to Cr(V) is the rate-determining step of the reaction. In addition, experimental stoichiometric analysis showed that a high valentCr(V) specie i...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2019
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6628261/ https://ncbi.nlm.nih.gov/pubmed/31125210 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b03890 |
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