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Exploring a Route to Cyclic Acenes by On‐Surface Synthesis

A route to generate cyclacenes by on‐surface synthesis is explored. We started by synthesizing two tetraepoxycyclacenes by sequences of Diels–Alder cycloadditions. Subsequently, these molecules were deposited onto Cu(111) and scanning‐tunneling‐microscopy(STM)‐based atom manipulation was employed to...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Schulz, Fabian, García, Fátima, Kaiser, Katharina, Pérez, Dolores, Guitián, Enrique, Gross, Leo, Peña, Diego
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6618096/
https://ncbi.nlm.nih.gov/pubmed/31026104
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201902784
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