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Site-selective C–H activation and regiospecific annulation using propargylic carbonates
Herein we describe an unprecedented Ru(II)-catalyzed site-selective and regiospecific annulation of benzoic acids with propargylic carbonates. The weakly coordinating carboxylic acid moiety outperformed other typically used directing groups in C–H activation, including ketone, nitrile, sulfonamide,...
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| 發表在: | Chem Sci |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6611066/ https://ncbi.nlm.nih.gov/pubmed/31341607 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01703h |
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