Mechanism of Olefin Metathesis with Neutral and Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes

[Image: see text] A series of neutral molybdenum imido alkylidene N-heterocyclic carbene (NHC) bistriflate and monotriflate monoalkoxide complexes as well as cationic molybdenum imido alkylidene triflate complexes have been subjected to NMR spectroscopic, X-ray crystallographic, and reaction kinetic...

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Publicat a:J Am Chem Soc
Autors principals: Herz, Katharina, Podewitz, Maren, Stöhr, Laura, Wang, Dongren, Frey, Wolfgang, Liedl, Klaus R., Sen, Suman, Buchmeiser, Michael R.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2019
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6595435/
https://ncbi.nlm.nih.gov/pubmed/31030510
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02092
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