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Enantioselective Total Syntheses of (+)-Fendleridine and (+)-Acetylaspidoalbidine

Enantioselective syntheses of hexacyclic aspidoalbidine alkaloids (+)-fendleridine (2) and (+)-acetylaspidoalbidine (3) are described. These syntheses feature an asymmetric decarboxylative allylation and photocyclization of a highly substituted enaminone. Also, the synthesis highlights the formation...

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Bibliografiske detaljer
Udgivet i:J Org Chem
Main Authors: Ghosh, Arun K., Born, Joshua R., Kassekert, Luke
Format: Artigo
Sprog:Inglês
Udgivet: 2019
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6594018/
https://ncbi.nlm.nih.gov/pubmed/30939004
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00145
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