[FeFe]‐Hydrogenase Mimic Employing κ(2)‐C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential

Two novel κ(2)‐C,N‐pyridine bridged [FeFe]‐H(2)ase mimics (1 and 2) have been prepared and are shown to function as efficient molecular catalysts for electrocatalytic proton reduction. The elemental and structural composition of the complexes are confirmed by NMR and IR spectroscopy, high‐resolution...

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Bibliographic Details
Published in:Eur J Inorg Chem
Main Authors: Schippers, Esther C. F., Nurttila, Sandra S., Oudsen, Jean‐Pierre H., Tromp, Moniek, Dzik, Wojciech I., van der Vlugt, Jarl Ivar, Reek, Joost N. H.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2019
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6582614/
https://ncbi.nlm.nih.gov/pubmed/31244551
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201900405
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