[FeFe]‐Hydrogenase Mimic Employing κ(2)‐C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential

Two novel κ(2)‐C,N‐pyridine bridged [FeFe]‐H(2)ase mimics (1 and 2) have been prepared and are shown to function as efficient molecular catalysts for electrocatalytic proton reduction. The elemental and structural composition of the complexes are confirmed by NMR and IR spectroscopy, high‐resolution...

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Bibliografski detalji
Izdano u:Eur J Inorg Chem
Glavni autori: Schippers, Esther C. F., Nurttila, Sandra S., Oudsen, Jean‐Pierre H., Tromp, Moniek, Dzik, Wojciech I., van der Vlugt, Jarl Ivar, Reek, Joost N. H.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2019
Teme:
Full Papers
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC6582614/
https://ncbi.nlm.nih.gov/pubmed/31244551
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201900405
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