[FeFe]‐Hydrogenase Mimic Employing κ(2)‐C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential

Two novel κ(2)‐C,N‐pyridine bridged [FeFe]‐H(2)ase mimics (1 and 2) have been prepared and are shown to function as efficient molecular catalysts for electrocatalytic proton reduction. The elemental and structural composition of the complexes are confirmed by NMR and IR spectroscopy, high‐resolution...

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Bibliografiske detaljer
Udgivet i:Eur J Inorg Chem
Main Authors: Schippers, Esther C. F., Nurttila, Sandra S., Oudsen, Jean‐Pierre H., Tromp, Moniek, Dzik, Wojciech I., van der Vlugt, Jarl Ivar, Reek, Joost N. H.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2019
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Full Papers
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6582614/
https://ncbi.nlm.nih.gov/pubmed/31244551
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201900405
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