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Beckmann rearrangement of nucleoside-5-oxime
The oxime of 5-formyl-2′-deoxyuridine (I) can be dehydrated by acetic anhydride to give 5-cyano-2′-deoxyuridine (II). In the HBr/acetic acid/acetic anhydride mixture I becomes rearranged to 5-N-acetamido-2-deoxyuridine (III). The pathway of this unexpected reaction is investigated.
Shranjeno v:
| izdano v: | Nucleic Acids Res |
|---|---|
| Main Authors: | , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Oxford University Press
1978
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6581401/ https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/1.suppl_1.s227 |
| Oznake: |
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