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Beckmann Rearrangement of Ketoximes Induced by Phenyl Dichlorophosphate at Ambient Temperature

Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.

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Detalhes bibliográficos
Publicado no:Molecules
Main Authors: Kuo, Chun-Wei, Hsieh, Min-Tsang, Gao, Shijay, Shao, Yi-Ming, Yao, Ching-Fa, Shia, Kak-Shan
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6268980/
https://ncbi.nlm.nih.gov/pubmed/23169264
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules171113662
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