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Protecting groups in nucleoside syntheses. IV. 5′-Halogeno-5′-deoxy-2′, 3′-cyclic sulphite isomers in the preparation of 5′-halogeno-5′-deoxy nucleosides

Two isomeric 5′-halogeno-2′,3′-sulphites, epimeric at sulphur atom, are formed from ribonucleosides with thionyl chloride-hexamethylphosphoric triamide reagent. The formation of 5′-chloro-2′,3′-sulphites with cytidine (95%) and/or adenosine (94%) in acetonitrile supports a new proposal of the reacti...

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Bibliografiske detaljer
Udgivet i:Nucleic Acids Res
Main Authors: Beránek, Jiří, Hřebabecký, Hubert
Format: Artigo
Sprog:Inglês
Udgivet: Oxford University Press 1978
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6581306/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/1.suppl_1.s125
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