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Stereoretentive Deuteration of α-Chiral Amines with D(2)O
We present the direct and stereoretentive deuteration of primary amines using Ru-bMepi (bMepi = 1,3(6’-methyl-2’-pyridylimino)isoindolate) complexes and D(2)O. High deuterium incorporation occurs at the α-carbon (70–99%). For α-chiral amines, complete retention of stereochemistry is achieved when us...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6578574/ https://ncbi.nlm.nih.gov/pubmed/27709928 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b07879 |
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