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Modeling Pyran Formation in the Molybdenum Cofactor: Protonation of Quinoxalyl-Dithiolene Promotes Pyran Cyclization
Mononuclear Mo and W enzymes require a unique ligand known as molybdopterin (MPT). This ligand binds the metal through a dithiolene chelate, and the dithiolene bridges a reduced pyranopterin group. Pyran scission and formation has been proposed as a reaction of the MPT ligand that may occur within t...
Shranjeno v:
| izdano v: | Inorg Chem |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2019
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6572731/ https://ncbi.nlm.nih.gov/pubmed/30942584 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b00194 |
| Oznake: |
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