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s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

Mixed s-block metal organometallic reagents have been successfully utilised in the catalytic intramolecular hydroalkoxylation of alkynols. This success has been attributed to the unique manner in which these reagents can overcome the challenges of the reaction: namely OH activation and coordination...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Fairley, Michael, Davin, Laia, Hernán-Gómez, Alberto, García-Álvarez, Joaquín, O'Hara, Charles T., Hevia, Eva
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6568277/
https://ncbi.nlm.nih.gov/pubmed/31293771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01598a
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