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s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

Mixed s-block metal organometallic reagents have been successfully utilised in the catalytic intramolecular hydroalkoxylation of alkynols. This success has been attributed to the unique manner in which these reagents can overcome the challenges of the reaction: namely OH activation and coordination...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Fairley, Michael, Davin, Laia, Hernán-Gómez, Alberto, García-Álvarez, Joaquín, O'Hara, Charles T., Hevia, Eva
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6568277/
https://ncbi.nlm.nih.gov/pubmed/31293771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01598a
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