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s-Block cooperative catalysis: alkali metal magnesiate-catalysed cyclisation of alkynols

Mixed s-block metal organometallic reagents have been successfully utilised in the catalytic intramolecular hydroalkoxylation of alkynols. This success has been attributed to the unique manner in which these reagents can overcome the challenges of the reaction: namely OH activation and coordination...

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Опубликовано в: :Chem Sci
Главные авторы: Fairley, Michael, Davin, Laia, Hernán-Gómez, Alberto, García-Álvarez, Joaquín, O'Hara, Charles T., Hevia, Eva
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2019
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC6568277/
https://ncbi.nlm.nih.gov/pubmed/31293771
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01598a
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