Synthesis of aminyl biradicals by base-induced Csp(3)–Csp(3) coupling of cationic azo dyes

The synthesis of the industrially important polymer parylene is achieved by polymerization of p-quinodimethane (p-QDM). The polymerization is thought to proceed via a biradical p-QDM dimer, but isolation or characterization of such a biradical has remained elusive. Here, we describe the synthesis of...

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Bibliografiska uppgifter
I publikationen:Chem Sci
Huvudupphovsmän: Liu, Yizhu, Varava, Paul, Fabrizio, Alberto, Eymann, Léonard Y. M., Tskhovrebov, Alexander G., Planes, Ophélie Marie, Solari, Euro, Fadaei-Tirani, Farzaneh, Scopelliti, Rosario, Sienkiewicz, Andrzej, Corminboeuf, Clémence, Severin, Kay
Materialtyp: Artigo
Språk:Inglês
Publicerad: Royal Society of Chemistry 2019
Ämnen:
Chemistry
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC6568049/
https://ncbi.nlm.nih.gov/pubmed/31293757
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc01502g
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