A Highly Active Bidentate Magnesium Catalyst for Amine‐Borane Dehydrocoupling: Kinetic and Mechanistic Studies

A magnesium complex (1) featuring a bidentate aminopyridinato ligand is a remarkably selective catalyst for the dehydrocoupling of amine‐boranes. This reaction proceeds to completion with low catalyst loadings (1 mol %) under mild conditions (60 °C), exceeding previously reported s‐block systems in...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Ried, Alexander C. A., Taylor, Laurence J., Geer, Ana M., Williams, Huw E. L., Lewis, William, Blake, Alexander J., Kays, Deborah L.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6563444/
https://ncbi.nlm.nih.gov/pubmed/30875128
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201901197
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