Release of Formic Acid from Copper Formate: Hydride, Proton‐Coupled Electron and Hydrogen Atom Transfer All Play their Role

Although the mechanism for the transformation of carbon dioxide to formate with copper hydride is well understood, it is not clear how formic acid is ultimately released. Herein, we show how formic acid is formed in the decomposition of the copper formate clusters Cu(II)(HCOO)(3) (−) and Cu(II)(2)(H...

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Bibliographic Details
Published in:Chemphyschem
Main Authors: Pascher, Tobias F., Ončák, Milan, van der Linde, Christian, Beyer, Martin K.
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2019
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6563433/
https://ncbi.nlm.nih.gov/pubmed/30958610
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cphc.201900095
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