Cargando...
Hydrogen Bonding to a Dinitrogen Complex at Room Temperature:Impacts on N(2) Activation
We report an experimental and computational analysis of the effects of hydrogen bonding to a metal dinitrogen complex. A series of H-bond donors over a wide pK(a) range (Δ 20) interact with the nitrogen unit of a Re(I)-(N(2)) complex at room temperature. Analysis by (15)N NMR, IR spectroscopy, assoc...
Gardado en:
| Publicado en: | J Am Chem Soc |
|---|---|
| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
|
| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6541522/ https://ncbi.nlm.nih.gov/pubmed/31083988 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b02288 |
| Tags: |
Engadir etiqueta
Sen Etiquetas, Sexa o primeiro en etiquetar este rexistro!
|